Product ID:CALCO UNLEADED GASOLINE
MSDS Date:03/24/1990
FSC:9130
NIIN:00-148-7103
MSDS Number: BHXDJ

CHEVRON ENVIRONMENTAL HEALTH CENTER INC.

15299 SAN PABLO AVE.
RICHMOND, CA 94804
US

Emergency Phone: 800-457-2022

Info Phone: 800-582-3835

Cage: 0AHD1

REDWOOD OIL CO AFFIL OF GIBSON OIL CO

428 SANTA ROSA, CA 95402 US

Telephone: 707-546-0766

Cage: 0G5C3

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: <1.4%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <1.4%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-XYLENE (P-DIMETHYLBENZENE) (SARA III)

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: <0.9%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

M-XYLENE (M-DIMETHYLBENZENE) (SARA III)

CAS: 108-38-3

RTECS: ZE2275000

Fraction By Weight: <4.6%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/15OSTEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <6.5%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 3.0%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 2.4%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <15.0%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <4.9%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

O-XYLENE (O-DIMETHYLBENZENE) (SARA III)

CAS: 95-47-6

RTECS: ZE2450000

Fraction By Weight: <2.2%

OSHA PEL 100PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT) IS >5 ML/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: PROLONGED OR FREQUENTLY
REPEATED CONTACT MAY CAUSE SKIN TO DEFAT AND IMPAIRMENT OF VISION.
INHALATION MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS, PULMONARY
EDEMA AND BRONCHITIS. CENTRAL NERVOUS S YSTEM EFFECTS, LUNG DAMAGE
IF SWALLOWEDOR ASPIRATED. CHRONIC: LIVER, KIDNEY AND BRAIN DAMAGE.
Explanation of Carcinogenicity:COMPONENTS OF GASOLINE ARE LISTED BY ALL
THREE AGENCIES.
Effects of Overexposure:EYES: PAIN, TEARS, SWELLING, REDNESS, BLURRED
VISION. SKIN: DRYNESS AND CRACKING. INHALE: HEADACHE, DIZZINESS,
LOSS OF APPETITE AND LOSS OF CORDINATION. HIGH CONCENTRATIONS MAY
CAUSE LOSS OF CONSCIOUS NESS, COMA AND DEATH. INGESTION MAY CAUSE
THE SAME SYMPTOMS AS INHALING ALONG WITH LUNG DAMAGE AND DEATH.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR
RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:
REMOV E CONTAMINATED CLOTHING. WASH WITH SOAPAND WATER. IF
IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE
VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE
MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:<-49F,<-45C
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING GASOLINE FIRES. THIS
PRODUCT PRESENTS AN EXTREME FIRE HAZARD.
Unusual Fire/Explosion Hazard:LIQUID VERY QUICKLY EVAPORATES, EVEN AT
LOW TEMPERATURES, AND FORMS VAPOR WHICH CAN CATCH FIRE AND BURN
WITH EXPLOSIVE VIOLENCE. EXTINGUISH ALL IGNITION SOURCES

Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION IN VICINITY
OF SPILL OR RELEASED VAPOR. CLEAN UP SMALL SPILLS USING APPROPRIATE
TECHNIQUES SUCH AS SORBENT MATERIALS OR PUMPING. WHERE FEASIBLE AND
APPROPRIATE REMOVE CONTAMINATED SOIL.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:NEVER SIPHON GASOLINE BY MOUTH. READ AND OBSERVE ALL
PRECAUTIONS ON PRODUCT LABEL. USE ONLY AS A MOTOR FUEL. DO NOT USE
FOR CLEANING, PRESSURE APPLIANCE FUEL, OR ANY OTHER SUCH USE.

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR
CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29
CFR 1910.134, INSTRUCTIONS/ WARNINGS AND NIOSH-RESPIRATOR
SELECTION.
Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE.
LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED.
Protective Gloves:NOT USUALLY NECESSARY.
Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.

HCC:F1
Boiling Pt:=25.C, 77.F
Vapor Pres:5-15
Vapor Density:3-4
Spec Gravity:0.7-0.8
Solubility in Water:INSOLUBLE
Appearance and Odor:ORANGE TO BRONZE LIQUID
Percent Volatiles by Volume:99+

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS CHLORATES, NITRATES, PEROXIDES, ETC.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:INCOMPLETE COMBUSTION CAN PRODUCE
CARBON MONOXIDE.

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.